曲剑萍 教授 Email:ias_jpqu@njtech.edu.cn
个人简介
2016年至今 南京工业大学，先进化学制造研究院，教授
2011-2015 海德堡大学化学系，博士后，洪堡学者(Günter Helmchen 教授)
2006-2011 上海有机化学研究所，理学博士（唐勇 研究员）
2001-2005 山东师范大学化学系，理学学士
研究方向
1.新型有机小分子光敏剂的设计、开发及在可见光催化的有机合成、功能聚合物合成中的应用；
2.基于可见光催化的新型不对称催化体系研究以及在手性合成中的应用
3.新型过渡金属催化剂的设计以及在有机合成新反应、配位聚合反应中的应用
4.新型功能聚合物的合成方法以及应用开发。
代表性论文
1. Iron-Catalyzed Aerobic α,β-Dehydrogenation. Guo-Qing Jiang, Bin-Hong Han, Xian-Peng Cai, Jian-Ping Qu*, and Yan-Biao Kang* Org. Lett. 2023, ASAP, DOI: 10.1021/acs.orglett.3c01240.
2. Endo/Exo-Controllable Photocyclization by EnT-SET-Switch. Xian-Peng Cai, Bin-Hong Han, Fu-Tong Cen, Jian-Ping Qu* and Yan-Biao Kang*. Org. Lett. 2023, 25, 2863–2867.
3. Ambient Temperature Dehydrogenative C(Ar)–H Carbonylative Lactamization of 2-Arylanilines Using DMF as C1-Source. Yong-Ze Chen, Ting-Hui Ding, Qiang-Qiang Li, Jian-Ping Qu and Yan-Biao Kang*. Org. Lett. 2023, 25, 2611–2615.
4. Reductive Cleavage of C–X or N–S Bonds Catalyzed by Super Organoreductant CBZ6.
Si-Da Wang, Bo Yang, Hao Zhang, Jian-Ping Qu* and Yan-Biao Kang*. Org. Lett. 2023, 25, 816–820.
5. Synthesis of Carbinoxamine via a-C(sp3)-H 2-pyridylation of O, S or N-containing compounds enabled by non-D-A-type super organoreductant and sulfoxide- or sulfide-HAT-reagents. Xian-Chao Cui, Hu Zhang, Yi-Ping Wang, Jian-Ping Qu,* Yan-Biao Kang*. Chem. Sci. 2022, 13, 11246–11251.
6. Direct synthesis of β-acyloxy aldehydes from linear allylic esters using O2 as the sole oxidant. Shu-Hui Lei, Ya Zhong, Xian-Peng Cai, Qing Huang, Jian-Ping Qu* and Yan-Biao Kang*. Org. Chem. Front. 2022, 9, 687-692.
7. tert-Butyl Nitrite as a Twofold Hydrogen Abstractor for Dehydrogenative Coupling of Aldehydes with N-Hydroxyimides. Peng-Fei Dai, Yi-Ping Wang, Jian-Ping Qu* and Yan-Biao Kang*. Org. Lett. 2021, 23, 9360–9364.
8. Direct Synthesis of β-Amino Aldehydes from Linear Allylic Esters Using O2 as the Sole Oxidant. Shu-Hui Lei, Ya Zhong, Xian-Peng Cai, Qing Huang, Jian-Ping Qu*, and Yan-Biao Kang*. Org. Lett. 2021, 23, 9273–9276.
9. α-Trideuteration of methylarenes. Lin Tie, Xiang-Huan Shan, Jian-Ping Qu,* Yan-Biao Kang,*Org. Chem. Front. 2021, 8, 2981
10. CBZ6 as a Recyclable Organic Photoreductant for Pinacol Coupling.Hua Wang, Jian-Ping Qu, and Yan-Biao Kang* Org. Lett. 2021, 23, 2900−2903
11. Iron-Catalyzed α,β-Dehydrogenation of Carbonyl Compounds, Xiao-Wei Zhang,§ Guo-Qing Jiang,§ Shu-Hui Lei, Xiang-Huan Shan, Jian-Ping Qu,* and Yan-Biao Kang* Org. Lett. 2021, 23, 1611−1615.
12. Discovery of Oxygen α‑Nucleophilic Addition to α,β-Unsaturated Amides Catalyzed by Redox-Neutral Organic Photoreductant. Zi-Hong Luan, Jian-Ping Qu, and Yan-Biao Kang*J. Am. Chem. Soc. 2020, 142, 20942−20947.
13. tBuOK-Promoted Cyclization of Imines with Aryl Halides. Ya-Wei Li, Hong-Xing Zheng, Bo Yang, Xiang-Huan Shan, Jian-Ping Qu,* and Yan-Biao Kang* Org. Lett. 2020, 22, 4553−4556.
14. Visible-Light-Induced, Base-Promoted Transition-Metal-Free Dehalogenation of Aryl Fluorides, Chlorides, Bromides, and Iodides Ting-Hui Ding, Jian-Ping Qu,* and Yan-Biao Kang* Org. Lett. 2020, 22, 3084−3088.
15. CuSO4-Catalyzed dual annulation to synthesize O, S or N-containing tetracyclic heteroacenes, Xiang-Huan Shan, Bo Yang, Jian-Ping Qu* and Yan-Biao Kang*, Chem. Commun. 2020, 56, 4063.
16. Recent Progress in C(Aryl)-C(Alkyl) Bond Cleavage of Alkylarenes, Peng-Fei Dai, Hua Wang, Xian-Chao Cui, Jian-Ping Qu* and Yan-Biao Kang*, Org. Chem. Front. 2020, 7, 820.
17. Deprotonated Salicylaldehyde as Visible Light Photocatalyst, Yan-Jun Zhuang, Jian-Ping Qu and Yan-Biao Kang*, J. Org. Chem. 2020, 85, 4386−4397.
18. Overcoming Electron-Withdrawing and Product-Inhibition Effects by Organocatalytic Aerobic Oxidation of Alkylpyridines and Related Alkylheteroarenes to Ketones, Hua Wang, Jie Liu, Jian-Ping Qu* and Yan-Biao Kang*, J. Org. Chem. 2020, 85, 4386−4397.
19. Regioselective Wacker-Type Oxidation of Internal Olefins in tBuOH Using Oxygen as the Sole Oxidant and tBuONO as the Organic Redox Cocatalyst, Qing Huang, Ya-Wei Li, Xiao-Shan Ning, Guo-Qing Jiang, Xiao-Wei Zhang, Jian-Ping Qu*, and Yan-Biao Kang*, Org. Lett. 2020, 22, 965-969.
20. CuSO4-Catalyzed Tandem C(sp3)–H Insertion Cyclization of Toluenes with Isonitriles to Form Indoles, Xiang-Huan Shan, Bo Yang, Jian-Ping Qu* and Yan-Biao Kang*, Org. Lett. 2020, 22, 357-360.
21. Radical α,β-Dehydrogenation of Saturated Amides via α-Oxidation with TEMPO under Transition Metal-Free Conditions. Mei-Mei Wang, Guo-Hui Sui, Xian-Chao Cui, Hui Wang, Jian-Ping Qu* and Yan-Biao Kang*, J. Org. Chem. 2019, 84, 8267-8274.
22. Competing Dehalogenation versus Borylation of Aryl Iodides and Bromides under Transition-Metal-Free Basic Conditions. Yi-Jie Niu, Guo-Hui Sui, Hong-Xing Zheng, Xiang-Huan Shan, Lin Tie, Jia-Le Fu, Jian-Ping Qu* and Yan-Biao Kang*, J. Org. Chem., 2019, 84, 10805-10813.
23. Cleavage of C(aryl)‐CH3 Bonds in the Absence of Directing Groups under Transition Metal Free Conditions, Peng-Fei Dai, Xiao-Shan Ning, Hua Wang, Xian-Chao Cui, Jie Liu, Jian-Ping Qu* and Yan-Biao Kang*, Angew. Chem. Int. Ed., 2019, 58, 5392-5395.
24. Copper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay, Xiang-Huan Shan, Hong-Xing Zheng, Bo Yang, Lin Tie, Jia-Le Fu, Jian-Ping Qu* and Yan-Biao Kang* Nature Commun. 2019, 10, 908.
25. Organocatalyzed Aerobic Oxidation of Aldehydes to Acids, Peng-Fei Dai, Jian-Ping Qu* and Yan-Biao Kang* Org. Lett. 2019, 21, 1393−1396.
26. Iridium-Catalyzed Asymmetric Allylic Substitution Reactions, Q. Cheng, H.-F. Tu, C. Zheng, J.-P. Qu, G. Helmchen,* Shu-Li You,* Chem. Rev. 2019, 119, 1855.
27. One-pot one-base conditions for two shots: organocatalyzed tandem isomerization-olefination of allylic alcohols, Hong-Xing Zheng, Jian-Ping Qu* and Yan-Biao Kang* Org. Chem. Front. 2018, 5, 2349.
28. Phenanthroline-tBuOK Promoted Intramolecular C–H Arylation of Indoles with ArI under Transition-Metal-Free Conditions, X.-H. Shan, B. Yang, H.-X. Zheng, J.-P. Qu*, Y.-B. Kang,* Org. Lett. 2018, 20, 7898.
29. Strategy for Overcoming Full Reversibility of Intermolecular Radical Addition to Aldehydes: Tandem C-H and C-O Bonds Cleaving Cyclization of (Phenoxymethyl)arenes with Carbonyls to Benzofurans, Hong-Xing Zheng, Xiang-Huan Shan, Jian-Ping Qu* and Yan-Biao Kang*, Org. Lett. 2018, 20, 3310.
30. Synthesis of Functionalized Indoles via Palladium-Catalyzed Aerobic Cycloisomerization of o-Allylanilines Using Organic Redox Cocatalyst, X.-S. Ning, M.-M. Wang, Qu, J.-P. Qu*, Y.-B. Kang,* J. Org. Chem. 2018, 83, 13523.
31. Tuning Regioselectivity of Wacker Oxidation in One Catalytic System: Small Change Makes Big Step, K.-F. Hu, X.-S. Ning, J.-P. Qu*, Y.-B. Kang,* J. Org. Chem. 2018, 83, 11327.
32. Pd-tBuONO Cocatalyzed Aerobic Indole Synthesis, Xiao-Shan Ning, Xin Liang, Kang-Fei Hu, Chuan-Zhi Yao, Jian-Ping Qu* and Yan-Biao Kang*. Adv. Synth. Catal. 2018, 360, 1590.
33. nBu4NOTf-Promoted Radical Self-Hydrogen Transferring Isomerization under Transition Metal-Free Conditions Hong-Xing Zheng, Chuan-Zhi Yao, Jian-Ping Qu* and Yan-Biao Kang* Org. Chem. Front. 2018, 5, 1213.
34. Synthesis of Highly Functionalized Indoles and Indolones via Selectivity-Switchable Olefinations, Ting-Hui Ding, Zu-Feng Xiao, Jian-Ping Qu* and Yan-Biao Kang*, J. Org. Chem. 2018, 83, 2467.
35. Direct Wittig Olefination of Alcohols, Qiang-Qiang Li, Zaher Shah, Jian-Ping Qu* and Yan-Biao Kang*. J. Org. Chem. 2018, 83, 296.
36. Applications of Iridium-Catalyzed Asymmetric Allylic Substitution Reactions in Target-Oriented Synthesis, J.-P. Qu, G. Helmchen*, Acc. Chem. Res. 2017, 50, 2539.
37. Dehydrogenative Synthesis of Linear α,β-Unsaturated Aldehydes with Oxygen at Room Temperature Enabled by tBuONO, Mei-Mei Wang, Xiao-Shan Ning, Jian-Ping Qu* and Yan-Biao Kang*, ACS Catal. 2017, 7, 4000.
38. Organopromoted Selectivity-Switchable Synthesis of Polyketones, Jie Liu, Kang-Fei Hu, Jian-Ping Qu* and Yan-Biao Kang*, Org. Lett. 2017, 19, 5593.
39. Transition-Metal-Free Hydrogenation of Aryl Halides: From Alcohol to Aldehyde, Hong-Xing Zheng, Xiang-Huan Shan, Jian-Ping Qu* and Yan-Biao Kang*, Org. Lett. 2017, 19, 5114.
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